Synthetic control of framework zinc purinate crystallisation and properties of a large pore, decorated, mixed-linker RHO-type ZIF.
نویسندگان
چکیده
A novel form of mixed-linker ZIF with the RHO topology is one of four zinc-imidazolate frameworks prepared with purine and 2-nitroimidazole. In this structure the linkers order to give a large pore solid with a high pore volume and an unusual symmetry and linker orientation. It possesses extra-framework zinc imidazolate units decorating the internal surface which can be removed to give high porosity.
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عنوان ژورنال:
- Chemical communications
دوره 48 53 شماره
صفحات -
تاریخ انتشار 2012